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Thulium (Tm)

Thulium (symbol Tm) is the chemical element with atomic number 69: a lanthanide (rare earth), solid at 0 °C, with an atomic mass of 168.93 u. Discovered in 1879 (Per Teodor Cleve).

Thulium is one of the least abundant lanthanides, which makes it costly and little used. It turns up in surgical lasers and portable X-ray machines. Its name evokes Thule, the mysterious far-northern land of the ancients.

Key facts

Atomic number
69
Symbol
Tm
French name
Thulium
Atomic mass
168.93 u
Molar mass
168.93 g/mol
Family
Lanthanides
Position
period 6, f-block
State at 0 °C
Solid
Melting point
1,544.9 °C
Boiling point
1,949.9 °C
Density
9.32 g/cm³
Electronegativity (Pauling)
1.25
First ionization energy
597 kJ/mol
Atomic radius
175 pm
Electron configuration
[Xe] 4f¹³ 6s²
Abundance in Earth's crust
0.52 ppm (62nd most abundant element)
Indicative price
3,000 $/kg (order of magnitude)
Radioactive
no
Discovery
1879, Per Teodor Cleve

Origin of the name

From Thule, the ancient name for a land in the far north.

What does thulium look like?

A silvery-gray metal soft enough to cut with a knife, fairly stable in air.

Where is thulium found?

About 0.5 ppm of Earth's crust: rare for a rare earth, yet still more abundant than silver. It accompanies the other heavy rare earths in xenotime and ionic clays.

Natural sources

  • Xenotime
  • Euxenite
  • Monazite
  • Ion-adsorption clays

How is thulium produced?

Separated by ion exchange, then reduced with lanthanum. World production is limited to a few tonnes a year.

Top producers

  • China
  • Myanmar

What is thulium used for?

  • Thulium-doped fiber lasers (2 micrometers) in urological surgery.
  • Thulium-170, an X-ray source for portable radiography devices.
  • Research into magnetic and superconducting materials.

In everyday life

  • Laser treatment of the prostate or urinary stones

Role in living things

No known biological role.

Hazards of thulium

Low toxicity; flammable dust. Thulium-170 is radioactive.

Cosmic origin

  • Neutron stars: Created when two neutron stars collide — the “forge” of gold.

History of thulium

Per Teodor Cleve identified it in 1879 in erbia and named it after Thule, a legendary land of the far north. In 1911 the American Charles James obtained pure thulium after some 15,000 successive recrystallizations of thulium bromate.

Did you know?

  • Charles James's 15,000 recrystallizations show just how hard rare earths are to separate.
  • Thulium-170 emits X-rays with no power supply, handy for radiography in the field.
  • It is the second least abundant lanthanide, after radioactive promethium.

Isotopes of thulium

Thulium has only one stable isotope, thulium-169. Irradiated in a reactor, it becomes thulium-170, a portable source of X-rays.

  • thulium-167: radioactive, half-life 9.25 days
  • thulium-169: 100% of natural thulium, stable
  • thulium-170: radioactive, half-life 129 days. A compact X-ray source for portable radiography, no electricity needed.
  • thulium-171: radioactive, half-life 1.92 years

Related elements

Same family (lanthanides): Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Ytterbium (Yb), Lutetium (Lu).