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Tungsten (W)

Tungsten (symbol W) is the chemical element with atomic number 74: a transition metal, solid at 0 °C, with an atomic mass of 183.84 u. Discovered in 1783 (Juan José and Fausto Elhuyar).

Tungsten melts at 3,422 °C, the all-time record among metals. Almost as dense as gold, it lit the world for a century as light-bulb filaments. Its carbide, extraordinarily hard, equips cutting tools and drill bits.

Key facts

Atomic number
74
Symbol
W
French name
Tungstène
Atomic mass
183.84 u
Molar mass
183.84 g/mol
Family
Transition metals
Position
period 6, group 6, d-block
State at 0 °C
Solid
Melting point
3,421.9 °C
Boiling point
5,929.9 °C
Density
19.25 g/cm³
Electronegativity (Pauling)
2.36
First ionization energy
759 kJ/mol
Atomic radius
135 pm
Electron configuration
[Xe] 4f¹⁴ 5d⁴ 6s²
Abundance in Earth's crust
1.25 ppm (57th most abundant element)
Indicative price
35 $/kg (order of magnitude)
Radioactive
no
Discovery
1783, Juan José and Fausto Elhuyar

Origin of the name

From the Swedish tung sten, “heavy stone”; the symbol W comes from wolfram.

What does tungsten look like?

A very dense (19.3 g/cm³), hard, steel-gray metal. When pure it is surprisingly ductile; when impure, brittle.

Where is tungsten found?

About 1 ppm of Earth's crust. It is extracted mainly from wolframite and scheelite.

Natural sources

  • Wolframite
  • Scheelite
  • Ferberite
  • Hübnerite

How is tungsten produced?

The ore is converted into ammonium paratungstate and then into oxide, which hydrogen reduces to tungsten powder. The powder is pressed and sintered (heated without melting), because the metal is too hard to melt.

Top producers

  • China
  • Vietnam
  • Russia
  • Bolivia

What is tungsten used for?

  • Tungsten carbide for cutting tools, drill bits and ballpoint-pen tips.
  • Incandescent bulb filaments and TIG welding electrodes.
  • Counterweights and the weights in phone vibration motors.
  • X-ray shielding and armor-piercing projectiles.
  • Competition darts.

In everyday life

  • A masonry drill bit
  • An incandescent light bulb
  • The ball of a ballpoint pen
  • Darts
  • A phone's vibration motor

Role in living things

It is the heaviest element known to play a biological role: some bacteria and archaea in hydrothermal vents use it in enzymes.

Hazards of tungsten

Mildly toxic. Tungsten carbide-cobalt dust can cause lung disease in workers.

Cosmic origin

  • Dying stars: Made slowly in red giants (stars like the Sun at the end of their lives).
  • Neutron stars: Created when two neutron stars collide — the “forge” of gold.

History of tungsten

The Swede Carl Wilhelm Scheele identified tungstic acid in 1781. In 1783 the Spanish brothers Juan José and Fausto Elhuyar isolated the metal from wolframite. Its name comes from the Swedish tung sten, “heavy stone”; its symbol W comes from “wolfram,” because the ore “devoured” tin like a wolf during smelting.

Did you know?

  • Since its density is almost identical to gold's, fake gold-plated bars with tungsten cores have been discovered.
  • An incandescent bulb filament runs at around 2,500 °C, a temperature almost no other metal could withstand.
  • The OSRAM brand comes from OSmium and wolfRAM, two filament metals.

Isotopes of tungsten

Tungsten has four stable isotopes plus a fifth, tungsten-180, which is radioactive with a half-life more than a hundred million times the age of the Universe.

  • tungsten-180: 0.12% of natural tungsten, radioactive, half-life 1.8 × 10¹⁸ years
  • tungsten-182: 26.5% of natural tungsten, stable
  • tungsten-183: 14.31% of natural tungsten, stable
  • tungsten-184: 30.64% of natural tungsten, stable
  • tungsten-186: 28.43% of natural tungsten, stable
  • tungsten-188: radioactive, half-life 69.8 days. Loaded into hospital generators to produce rhenium-188 on demand.

Related elements

Same family (transition metals): Scandium (Sc), Titanium (Ti), Vanadium (V), Chromium (Cr), Manganese (Mn), Iron (Fe), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Yttrium (Y), Zirconium (Zr), Niobium (Nb), Molybdenum (Mo), Technetium (Tc), Ruthenium (Ru), Rhodium (Rh), Palladium (Pd), Silver (Ag), Cadmium (Cd), Hafnium (Hf), Tantalum (Ta), Rhenium (Re), Osmium (Os), Iridium (Ir), Platinum (Pt), Gold (Au), Mercury (Hg), Rutherfordium (Rf), Dubnium (Db), Seaborgium (Sg), Bohrium (Bh), Hassium (Hs).

Same column (group 6): Chromium (Cr), Molybdenum (Mo), Seaborgium (Sg).